Historical Development Of The Concept Of Element
The modern concept of an element is unambiguous, depending as it does on the use of chemical and physical processes as a means of discriminating elements from compounds and mixtures. The existence of fundamental substances from which all matter is made, however, has been the basis of much theoretical speculation since the dawn of history. The ancient Greek philosophers Thales, Anaximenes, and Heracleitus each suggested that all matter is composed of one essential principle—or element. Thales believed this element to be water; Anaximenes suggested air; and Heracleitus, fire. Another Greek philosopher, Empedocles, expressed a different belief—that all substances are composed of four elements: air, earth, fire, and water. Aristotle agreed and emphasized that these four elements are bearers of fundamental properties, dryness and heat being associated with fire, heat and moisture with air, moisture and cold with water, and cold and dryness with earth. In the thinking of these philosophers all other substances were supposed to be combinations of the four elements, and the properties of substances were thought to reflect their elemental compositions. Thus, Greek thought encompassed the idea that all matter could be understood in terms of elemental qualities; in this sense, the elements themselves were thought of as nonmaterial. The Greek concept of an element, which was accepted for nearly 2,000 years, contained only one aspect of the modern definition—namely, that elements have characteristic properties.
In the latter part of the Middle Ages, as alchemists became more sophisticated in their knowledge of chemical processes, the Greek concepts of the composition of matter became less satisfactory. Additional elemental qualities were introduced to accommodate newly discovered chemical transformations. Thus, sulfur came to represent the quality of combustibility, mercury that of volatility or fluidity, and salt that of fixity in fire (or incombustibility). These three alchemical elements, or principles, also represented abstractions of properties reflecting the nature of matter, not physical substances.
The structure of atoms
Atoms of elemental substances are themselves complex structures composed of more fundamental particles called protons, neutrons, and electrons. Experimental evidence indicates that, within an atom, a small nucleus, which generally contains both protons and neutrons, is surrounded by a swarm, or cloud, of electrons. The fundamental properties of these subatomic particles are their weight and electrical charge. Whereas protons carry a positive charge and electrons a negative one, neutrons are electrically neutral. The diameter of an atom (about 10−8 centimetre) is 10,000 times larger than that of its nucleus. Neutrons and protons, which are collectively called nucleons, have relative weights of approximately one atomic mass unit, whereas an electron is only about 1/2000 as heavy. Because neutrons and protons occur in the nucleus, virtually all of the mass of the atom is concentrated there. The number of protons in the nucleus is equivalent to the atomic number of the element. The total number of protons and neutrons is called the mass number because it equals the relative weight of that atom compared to other atoms. Because the atom itself is electrically neutral, the atomic number represents not only the number of protons, or positive charges, in the nucleus but also the number of electrons, or negative charges, in the extranuclear region of the atom
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